Energy of the electron in the nth state of an atom = -13.6z²/n² eV
Here, z is the atomic number of the atom.
For the hydrogen atom, z is equal to 1.
Energy required to excite an atom from the initial state (ni) to the final state (nf) = -13.6/nf² + 13.6/ni² eV
This energy must be equal to or less than the energy of the incident electron beam.
∴ -13.6/nf² + 13.6/ni² eV = 12.5
(Energy of the electron in the ground state = -13.6/1² = -13.6 eV)
-13.6/nf² + 13.6 eV = 12.5
→ 13.6 - 12.5 = 13.6/nf²
→ 1.1 = 13.6/nf²
→ nf² = 13.6/1.1 = 12.36
→ nf = √12.36 = 3.51
Since nf can't be a fraction
∴ nf = 3
Hence hydrogen atom would be excited upto 3rd energy level
First member of lyman: 1/λH = RH(1)²[1/1² - 1/2²]
R = 1.097 × 10⁷ m⁻¹
λ = 1215 Å
First member of Balmer: 1/λ23 = RH(1)²[1/2² - 1/3²]
λ = 6563 Å