at θ=60°, the block will start sliding down the plane and on further increasing θ, it will topple at certain θ.
at θ=60°, the block will start sliding down the plane and continue to do so at higher angles.
at θ=30°, the block will start sliding down the plane.
the block will remain at rest on the plane up to certain θ and then it will topple.
As we increase the angle of inclination, the frictional force acts in the upward direction on the incline to prevent sliding of the block. But this frictional force also causes torque about the CoM of the block, which is countered by the torque due to the Normal force on the block. But as the angle of inclination θ increases, the normal force reduces and the perpendicular distance of the Normal force from the CoM also reduces, which decreases the counter-torque due to the normal force. So after an angle, the torque due to frictional force overcomes that due to the normal force, and the block starts to topple.