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Question:

A variable, opposite external potential (Eext) is applied to the cell Zn|Zn2+(1M)||Cu2+(1M)|Cu, of potential 1.1 V. When Eext < 1.1 V and Eext > 1.1 V respectively electron flow from:

cathode to anode in both cases

cathode to anode and anode to cathode

anode to cathode and cathode to anode

anode to cathode in both cases

Solution:

When Eext < 1.1 V, the electrons will flow from anode to cathode, the cell will act as the galvanic cell. When Eext > 1.1 V, electrons will flow from cathode to anode and the cell will act as an electrolytic cell. Hence, option B is correct.