CH3−CH|CH3COOH
CH3CH2COOH
CH3CH2CH2COOH
CH3COOH
The compound A is propionic acid CH3CH2COOH. Propionic acid reacts with ammonia to form ammonium propionate. On heating, ammonium propionate is converted to propionamide. Hoffmann bromamide reaction in presence of KOH and bromine converts propionamide to ethyl amine. In this process, one carbon atom is lost.
CH3−CH2−COOH + NH3 → CH3−CH2−COO⁻ + NH4⁺
Δ → CH3−CH2−CONH2
KOH + Br2 → CH3−CH2−NH2
(A) (B) (C)