devarshi-dt-logo

Question:

Bromine is added to cold dilute aqueous solution of NaOH. The mixture is boiled. Which of the following statements is not true?

The greatest difference between the various oxidation states of bromine is 5

During the reaction bromine is present in four different oxidation states

On acidification of the final mixture bromine is formed

Disproportionation of bromine occurs during the reaction

Solution:

On acidification the final mixture gives bromine: 5NaBrO + NaBrO3 + 6HCl → 6NaCl + 3Br2 + 3H2O. Thus, during the reaction, bromine is present in four different oxidation states i.e., zero in Br2, +1 in NaBrO, -1 in NaBr, and +5 in NaBrO3. The greatest difference between various oxidation states of bromine is 6 and not 5. On acidification of the final mixture, Br2 is formed and disproportionation of Br2 occurs during the reaction giving BrO⁻, Br⁻ and BrO3⁻ ions. Hence, option A is correct.