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Question:

Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their _________.

formation of intramolecular H-bonding

formation of intermolecular H-bonding

more extensive association of carboxylic acid via van der Waals force of attraction

formation of carboxylate ion

Solution:

Carboxylic acids have higher boiling points than aldehydes, ketones, and given alcohol of comparable molecular mass. This is because of formation of intermolecular H-bonding.