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sodium chloride, calcium chloride
potassium chloride, sodium chloride
calcium chloride, magnesium chloride
Water described as "hard" is high in dissolved minerals, specifically calcium and magnesium. Calcium and magnesium dissolved in water are the two most common minerals that make water "hard." Calcium chloride and magnesium chloride can be dissolved in distilled water to make it hard. Hence, calcium chloride and magnesium chloride when dissolved in water make it hard. Therefore, option D is correct.