Na
K
Rb
Li
All the alkali metal ions exist as hydrated ions M+(H₂O)ₙ in their aqueous solutions. The degree of hydration decreases as the ionic size increases when we go down the group. Since the mobility of ions is inversely proportional to the size of their hydrated ions, the increasing order of ionic mobility is Li+ < Na+ < K+ < Rb+. Therefore, Li+ has the lowest ionic mobility.