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Question:

Match the orbital overlap figures shown in List-I with the description given in List-II and select the correct answer using the code given below the lists.

P𕒶,Q𕒵,R𕒷,S𕒸

P𕒶,Q𕒷,R𕒵,S𕒸

P𕒸,Q𕒷,R𕒵,S𕒶

P𕒸,Q𕒵,R𕒷,S𕒶

Solution:

P is overlapping of two orbitals of dx²−y² and is bonding=d-d σ bonding-2
Q is overlap of py and dxy, thus its π overlap and is bonding-p-d π bonding-3
R is overlap of py and dxy, thus its π overlap and is antibonding p-d π bonding-1
S is overlap of dz² and dx²−y², thus its σ overlap and is anti-bonding-d-d σ bonding-4
P𕒶, Q𕒷, R𕒵, S𕒸