More reactive towards nucleophilic substitution reaction. So, nucleophilic substitution means nucleophiles are attacking and benzene acts as an electrophile. As we know, the more electron-withdrawing groups present on benzene, the more electrophilic the benzene ring becomes. In B, we have a NO2 group attached to the ring. NO2 is a strong electron-withdrawing group, so it makes benzene more electrophilic as it pulls electron density towards itself. Therefore, B is more reactive towards nucleophilic substitution.