Similar in hybridization for the central atom with different structures
Isostructural with same hybridization for the central atom
Dissimilar in hybridization for the central atom with different structures
Isostructural with different hybridization for the central atom
a. In NO3-, Hybridisation = 1/2[5 + 0 + 1] = 3. Thus, in NO3-, the central atom is sp2 hybridised and it has trigonal planar geometry.
In H3O+, Hybridisation = 1/2[6 + 3 - 1] = 4. Thus, in H3O+, the central atom is sp3 hybridised and it has pyramidal geometry.
Therefore, NO3- and H3O+ are dissimilar in hybridization for the central atom with different structures.