The chloride that cannot get hydrolysed is: SiCl4, PbCl4, CCl4, SnCl4
SiCl4
CCl4
SnCl4
PbCl4
Solution:
CCl4 doesn't undergo hydrolysis because of the absence of vacant d-orbitals. But in SiCl4, silicon has vacant d-orbitals which can be used for hydrolysis. Hence SiCl4 can undergo hydrolysis.