H2S2O7>H2SO4>H2SO3
H2SO4>H2S2O7>H2SO3
H2S2O7>H2SO3>H2SO4
H2SO3>H2SO4>H2S2O7
The correct sequence of decreasing number of pi-bonds is H2S2O7(4) > H2SO4(2) > H2SO3(1). The numbers in bracket indicate the number of pi bonds.