devarshi-dt-logo

Question:

The correct statements among (a) to (d) are:
(a) saline hydrides produce H2 gas when reacted with H2O.
(b) Reaction of LiAlH4 with BF3 leads to B2H6.
(c) PH3 and CH4 are electron-rich and electron-precise hydrides, respectively.
(d) HF and CH4 are called as molecular hydrides.

(a), (b), (c) and (d)

(a), (c) and (d) only

(c) and (d) only

(a), (b) and (c) only

Solution:

Correct option is C.
(a) M⁻H⁺ + H₂O → MOH + H₂
Ionic hydride/saline hydride
(b) 4BF₃ + 3LiAlH₄ → 2B₂H₆ + 3LiF + 3AlF₃
(c) Ref, image
(d) HF and CH₄ are molecular hydrides because they are covalent molecules.