Entropy of adsorption is negative.
On adsorption, decrease in surface energy appears as heat.
Enthalpy of adsorption is negative.
On adsorption, the residual forces on the surface are increased.
(A) Enthalpy of adsorption is negative as heat is liberated during adsorption. The process is exothermic. Hence, statement A is correct (B) On adsorption, the residual forces on the surface are decreased as the surface is covered with the substance being adsorbed which develops forces between absorbate and adsorbent. Hence, statement B is incorrect (C) On adsorption decreases in surface energy appears as heat. This makes the process exothermic. Thus, statement C is correct (D) Entropy of adsorption is negative as there is a decrease in the disorder. Hence, the statement D is correct.