[CaF2]
[3Ca3(OH)2.CaF2]
[3Ca3(PO4)2.CaF2]
[3(CaF2).Ca(OH)2]
The Fluoride ion converts [3Ca3(PO4)2.Ca(OH)2] to [3Ca3(PO4)2.CaF2]. The reaction can be given as follows: [3Ca3(PO4)2.Ca(OH)2] (drinking water up to 1 ppm) + 2F⁻ → [3Ca3(PO4)2.CaF2] (harder teeth enamel) Hence, the correct option is [3Ca3(PO4)2.CaF2]