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Question:

The time for half-life period of a certain reaction A→products is 1 hour. When the initial concentration of the reactant A is 2.0 mol L⁻¹, how much time does it take for its concentration to come from 0.50 to 0.25 mol L⁻¹ if it is a zero-order reaction?

4 h

0.5 h

1 h

0.25 h

Solution:

For a zero order reaction
k = x/t → (1)
Where x = amount decomposed
For a zero order reaction,
k = [A]₀ / 2t₁₂
Since [A₀] = 2M, t₁₂ = 1hr; k = 1
From equation (1), t = 0.25/1 = 0.25hr