Critical angle is given by: θc=sin⁻¹(1/μ)
For ray 1, i=45°=sin⁻¹(1/1.414)
θc1=sin⁻¹(1/1.35)>sin⁻¹(1/1.414)
Hence, θc1>i
Ray will not undergo total internal reflection.
Applying Snell's law, 1.35sin(45°)=1sin(θr)
sin(θr)=0.9545
θr≈72°
For ray 2, i=45°=sin⁻¹(1/1.414)
θc2=sin⁻¹(1/1.45)
θc2=sin⁻¹(1/1.45)<sin⁻¹(1/1.414)
Hence, θc1<i
Ray will undergo total internal reflection.