Physisorption Chemisorption
- Physisorption is non- specific in nature. It involves Waal’s interaction between adsorbate and adsorbent. 1. Chemisorption is highly specific in nature as it involves chemical bond formation between adsorbate and adsorbent.
- On increasing the temperature physisorption decreases. 2. On increasing the temperature chemisorption increases.
- Physisorption is reversible in nature. 3. Chemisorption is irreversible in nature.
- In the case of physisorption, the enthalpy change is small.
- In the case of chemisorption, the enthalpy change is high.
One similarity between physisorption and chemisorption: both increase with an increase in surface area.