Write the chemical reactions involved in the process of extraction of Gold. Explain the role of dilute NaCN and Zn in this process.
Solution:
Dilute NaCN solution is used in presence of oxygen (from air) for leaching gold sample. 4Au(s)+8CN⁻(aq)+2H₂O(aq)+O₂(g)→4[Au(CN)₂]⁻(aq)+4OH⁻(aq) Zinc displaces gold from the complex [Au(CN)₂]⁻(aq). Zn(s)+2[Au(CN)₂]⁻(aq)→[Zn(CN)₄]²⁻(aq)+2Au(s)